Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of AuCu(dpnapy)(3)ClO4(2) and AuCd(dpnapy)(3)ClO4(3)

Chan WH.; Mak TCW.; Che CM.Cheung KK.

首页> 外文期刊>Journal of the Chemical Society, Dalton Transactions.Inorganic Chemistry >Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of AuCu(dpnapy)(3)ClO4(2) and AuCd(dpnapy)(3)ClO4(3)

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Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of AuCu(dpnapy)(3)ClO4(2) and AuCd(dpnapy)(3)ClO4(3)

机译：7-二苯基膦-2,4-二甲基-1,8-萘啶（dpnapy）的金（I）络合物作为金属配体，用于封装金属离子。AuCu（dpnapy）（3）ClO4（2）和AuCd（dpnapy）（3）ClO4（3）的晶体结构

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Reaction of dpnapy dpnapy = 7-diphenylphosphino-2,4-dimethyl- 1,8-naphthyridine with Au(tht)Cl (tht = tetrahydrothiophene) in dichloromethane afforded Au(dpnapy)(3)(+), which shows a strong affinity towards Cu-I and Cd-II ions; crystal structures of AuCu(dpnapy)(3)ClO4(2) and AuCd(dpnapy)(3)ClO4(3) revealed that Au(dpnapy)(3)(+) functions as a metalloligand with the three naphthyridyl groups positioned in a trigonal fashion. References: 7

机译：dpnapy [dpnapy = 7-二苯基膦-2,4-二甲基-1,8-萘啶] 与 [Au（tht）Cl] （tht = 四氢噻吩）在二氯甲烷 [Au（dpnapy）（3）]（+）中的反应，对 Cu-I 和 Cd-II 离子具有很强的亲和力;[AuCu（dpnapy）（3）][ClO4]（2）和[AuCd（dpnapy）（3）][ClO4]（3）的晶体结构表明，[Au（dpnapy）（3）]（+）作为金属配体，三个萘啶基呈三角形排列。[参考文献： 7]

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《Journal of the Chemical Society, Dalton Transactions.Inorganic Chemistry》 |1998年第6期|873-874|共2页
作者
Chan WH.; Mak TCW.; Che CM.Cheung KK.;
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Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China.;

harm.gu.se;

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正文语种英语
中图分类无机化学;
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Luminescent;

机译：发光的;

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1. Synthesis, structure and spectroscopic properties of [Cu-3(mu-dpnapy)(3)(CH3CN)][ClO4](3)center dot CH3CN (dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array [J] . Chan WH., Che CM., Peng SM. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第17期

机译：[Cu-3（mu-dpnapy）（3）（CH3CN）] [ClO4]（3）中心点CH3CN的合成，结构和光谱性质（dpnapy = 7-二苯基膦基-2,4-二甲基-1,8-萘啶）带有线性铜原子阵列
2. Synthesis, Crystal Structures and Magnetic Properties of a Linear Trinuclear Cu(II) Complex Cu-3(ClCH2COO)(6)(bpy)(2) and a Dinuclear Complex Cu-2(bpy)(2)(mu-OH)(mu-OH2) (mu-ClCH2COO)(ClO4)(2) [J] . Thatipamula Krishna Chary, Bhargavi Govindugari, Rajasekharan Melath V chemistryselect . 2019,第12期

机译：Synthesis, Crystal Structures and Magnetic Properties of a Linear Trinuclear Cu(II) Complex Cu-3(ClCH2COO)(6)(bpy)(2) and a Dinuclear Complex Cu-2(bpy)(2)(mu-OH)(mu-OH2) (mu-ClCH2COO)(ClO4)(2)
3. Synthesis of tris- and tetrakis(pyrazol-1-yl)borate gold(III) complexes. Crystal structures of Au{kappa(2)-N,N '-BH(Pz)(3)}Cl-2 (pz = pyrazol-1-yl) and Au{kappa(2)-N,N '-B(Pz)(4)} (kappa(2)-C,N-C6H4CH2NMe2-2)ClO4 center dot CHCl3 [J] . Vicente J., Chicote MT., Guerrero R.Herber U. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第7期

机译：Synthesis of tris- and tetrakis(pyrazol-1-yl)borate gold(III) complexes. Crystal structures of Au{kappa(2)-N,N '-BH(Pz)(3)}Cl-2 (pz = pyrazol-1-yl) and Au{kappa(2)-N,N '-B(Pz)(4)} (kappa(2)-C,N-C6H4CH2NMe2-2)ClO4 center dot CHCl3

Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions. Crystal structures of AuCu(dpnapy)(3)ClO4(2) and AuCd(dpnapy)(3)ClO4(3)

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