Unimolecular decay paths of electronically excited species. VI. TheAtilde;2Estate of NH+3

摘要

TheAtilde;thinsp;2Estate of the NH+3ion is split by a Jahnndash;Teller interaction. The potential energy surface of the2Alsquo;component of stateAtilde; undergoes a conical intersection with the surface of the ground state. This brings about an ultrafast relaxation channel.