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Structure characterization and adsorption properties of tetraethylenepentamine ion exchange fiber

机译:四乙烯戊胺离子交换纤维的结构表征及吸附性能

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摘要

A novel tetraethylenepentamine ion exchange fiber (TAIEF) was prepared using polypropylene grafted styrene (PP-g-ST) fiber as raw material. The chemical structure of TAIEF was characterized using infrared spectrum (IR) method. TAIEF had good appearance and shape after reaction in SEM images, the TGA curves revealed that both PP-g-ST fiber and acetyl PP-g-ST fiber had good thermal stability below 250 degrees C, and the weight loss rate of TAIEF is 9 from 50 degrees C to 200 degrees C obtained by TGA. TAIEF adsorption capacity to Fe(III) is larger than that of In(III) in the pH value 1.00 to 3.00, while the pH value is at 2.50 to 3.00, TAIEF adsorption capacity to Fe(II) and Zn(II) are smaller than that of In(III). The selective adsorption ability to Fe(III) is higher than In(III), and the selective absorptivity to In(III) is better than Fe(II) and Zn(II). The mechanism was explained of TAIEF favorable selective adsorption to In(III) and Fe(III) ions in mixed solutions. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44513.
机译:以聚丙烯接枝苯乙烯(PP-g-ST)纤维为原料,制备了一种新型四乙烯五胺离子交换纤维(TAIEF)。采用红外光谱(IR)方法对TAIEF的化学结构进行了表征。在SEM图像中,TAIEF反应后具有良好的外观和形状,TGA曲线显示PP-g-ST纤维和乙酰PP-g-ST纤维在250°C以下均具有良好的热稳定性,TGA得到的TAIEF在50°C至200°C的失重率为9%。在pH值为1.00-3.00时,TAIEF对Fe(III)的吸附能力大于In(III),而pH值为2.50-3.00时,TAIEF对Fe(II)和Zn(II)的吸附能力小于In(III)。对Fe(III)的选择性吸附能力高于In(III),对In(III)的选择性吸附率优于Fe(II)和Zn(II)。解释了TAIEF对混合溶液中In(III)和Fe(III)离子的有利选择性吸附的机理。(c) 2016 Wiley Periodicals, Inc. J. Appl. Polym.科学 2017, 134, 44513.

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