Temperature dependence ofV rarr; R, Tenergy transfer probabilities in CO2(00deg;1) plus; HFsol;DF

摘要

Temperature dependence of vibration to rotationhyphen;translation energy transfer probabilities in CO2(00deg;1)plus;HFsol;DFrarr;CO2(n ml0) plus; HFsol;DF has been investigated in the range 300ndash;1000deg;K. It is shown that the negative temperature dependence of transition probabilities at lower temperatures and the appearance of the probability minimum at intermediate temperatures are due to the influence of hydrogen bond interaction.