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Excess volume of oligomer blends: A numerical study

机译:Excess volume of oligomer blends: A numerical study

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The thermodynamic equation of state for oligomer systems of different densities and flexibilities was studied by numerical Monte Carlo simulations. The values for the thermodynamic limit (Vrarr;infin;) are obtained by a finite size scaling from the numerical values calculated for the small simulation volume. The present numerical results give a good explanation of the thermodynamic behavior of oligomer mixtures as a function of the composition ratio fgr;.

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