The N(~4S) + H_2O(X~1#SIGMA#)Reaction

摘要

The title reaction, which is spin-forbidden for N_2(X~1#SIGMA#_g~+)+NO(X~2II) production, has been studied from 960 to 1130 K in a high-temperature photochemistry reactor. No reaction could be observed, indicating k < 1 X 10~(15) cm~3. It is concluded that there is no significant contribution from the spin-allowed exothermic path leading to N_2(X~1#SIGMA#_g~+) + NO(a~4II).