首页> 外文期刊>journal of chemical physics >Generalized Secondhyphen;Order Macroscopic Transport Equations
【24h】

Generalized Secondhyphen;Order Macroscopic Transport Equations

机译:Generalized Secondhyphen;Order Macroscopic Transport Equations

获取原文
           

摘要

A complete set of macroscopic transport equations suitable for application to experiment is obtained from nonequilibrium thermodynamics. Full account is taken of (i) bulk flow, (ii) conservative external fields (gravitational, centrifugal, and electrostatic), (iii) pressure gradients, and (iv) nonconstancy of thermodynamic and transport coefficients. There result 4(v+1) independent partial differential equations for avhyphen;component system. Four of the equations involve only barycentric velocity, external fields, density, viscosity, and pressure. Independent secondhyphen;order equations are obtained for the temperature distribution andvminus;1 mass fraction distributions. The remaining 3vequations can be used to calculate the vectorial heat and diffusion fluxes. In order to take account of nonconstancy of viscosities, diffusivities, etc., a Taylor's series expansion in the spatial coordinates is suggested. A perturbationmdash;iteration scheme can then be used to solve the transport equations for the velocities, the fluxes, and the distributions of temperature, pressure, andvminus;1 mass fractions. The solutions are polynomials in thermodynamic derivatives of the thermodynamic and transport coefficients.

著录项

获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号