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>Fluorescence quenching in micelles: A theoretical model for the intramicellar first order quenching rate constant
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Fluorescence quenching in micelles: A theoretical model for the intramicellar first order quenching rate constant
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机译:Fluorescence quenching in micelles: A theoretical model for the intramicellar first order quenching rate constant
Considering the fact that in a micellar medium solubilized molecules are mostly present near the surface, a solution of Fickrsquo;s diffusion law on a spherical surface is obtained to calculate the rate of diffusion controlled reactions in a micelle. It is shown that transients are small. Corrections are applied for the radial distribution of probe and quencher. The model is extended to reactions slower than diffusion controlled.
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