Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis(imidazolidine)-derived Pincer Rh Complex

Arai Takayoshi; Tosaka Takuya; Kuwano Satoru

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Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis(imidazolidine)-derived Pincer Rh Complex

机译：Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis(imidazolidine)-derived Pincer Rh Complex

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摘要

A chiral bis(imidazolidine) NCN-rhodium complex (tBu-PhBidine-Rh(OAc)(2): cat 2) catalyzed the asymmetric Mannich reaction of malononitrile with isatin-derived imines, which provided an efficient synthetic route for 3-amino-2-oxoindoline-3-carboxylates.

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来源
《chemistryselect》 |2017年第24期|7368-7371|共4页
作者
Arai Takayoshi; Tosaka Takuya; Kuwano Satoru;
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作者单位

Chiba Univ;

Chiba Univ;

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正文语种英语
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asymmetric catalysis; isatin; malononitrile; Mannich; pincer complex; HIGHLY ENANTIOSELECTIVE SYNTHESIS; ORGANOCATALYTIC ALPHA-AMINATION; AZA-HENRY REACTION; 3-ISOTHIOCYANATO OXINDOLES; MICHAEL ADDITION/CYCLIZATION; 1,3-DIPOLAR CYCLOADDITION; ISOTHIOCYANATO OXINDOLES; CASCADE REACTION; KETIMINES; CONSTRUCTION;

Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis(imidazolidine)-derived Pincer Rh Complex

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