Supramolecular Complexation between Porphyrin-Viologen Dyad and Cucurbit7uril

摘要

abstract_textpWe here report the synthesis of a porphyrin-viologen dyad, and its supramolecular complexation with cucurbit7uril (CB7). The synthesized dyad was characterized by (HNMR)-H-1 spectroscopy and ESI mass spectrometry. The dyad readily forms a stable 1:1 supramolecular complex with CB7, as evidenced by (HNMR)-H-1, ESI mass spectrometry, and isothermal titration calorimetry. The formation constant for the 1:1 complex determined by the photometric titration is (5.5 +/- 0.2) x 10(4) M-1 at 25 degrees C in DMSO, which is nearly consistent with that obtained by titration calorimetry. We also uncovered the shuttling motion of the CB7 ring in the supramolecular complex by variable temperature experiments in (HNMR)-H-1 spectroscopy. Influences on the fluorescence of dyad by the supramolecular complexation with CB7 was investigated in DMSO. When CB7 was added to a solution of the dyad, the fluorescence intensities of dyad remarkably diminish accompanying with shifts to shorter wavelengths. While the electrochemical behavior of dyad in DMSO exhibits six redox waves, the redox waves exhibit irreversible behaviors in the presence of CB7./p/abstract_text