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Role of molecular parameters during flow of polymer solutions in unconsolidated porous media

机译:聚合物溶液在未固结多孔介质中流动过程中分子参数的作用

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AbstractIn order to understand the molecular behavior of polymers during flow through porous media, five polymers with varying degree of amide‐carboxylate group ratio in partially hydrolyzed polyacrylamides were selcted, and the flow properties of their dilute solutions were measured in unconsolidated porous media. It has been found that adsorption of the polymers at the surface during flow, which plays an important role in permeability reduction, largely depends on the flexibility of the linear chains and electrostatic nature of the porous matrix. The flexibility of the chain is explained on the nature and ratio of groups attached on linearCCChains, e.g., varying degree of NH2and COOH groups in partially hydrolyzed polyacrylamides in the exp
机译:摘要为了解聚合物在多孔介质中流动过程中的分子行为,选取了5种不同程度的酰胺-羧酸酯基团比的聚合物在部分水解聚丙烯酰胺中,并测定了其稀溶液在未固结多孔介质中的流动特性。研究发现,聚合物在流动过程中在表面的吸附在降低渗透率方面起着重要作用,这在很大程度上取决于线性链的柔韧性和多孔基体的静电性质。链的柔韧性通过线性CC链上连接的基团的性质和比例来解释,例如,exp中部分水解聚丙烯酰胺中不同程度的NH2和COOH基团

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