Effect of processing parameters, applied pressure and temperature on the electrical resistivity of rubber-based conductive composites

摘要

Carbon black-and short carbon fibre (SCF)-filled conductive composites were prepared from ethylene vinyl acetate (EVA), ethylene propylene diene (EPDM) rubber and their 50:50 blend. The electrical resistivity of carbon black-and SCF-filled composites were measured under different conditions. The electrical conductivity of filled polymer composites is due to the formation of a continuous conductive network in the polymer matrix. These conductive networks involve specific arrangement of conductive elements so that the electrical paths are formd for free movement of electrons. it was found that electrical conductivity of filled conductive composites depends on different processing parameters like mixing time, rotor speed, mixing temperature, vulcanization time and pressure and service conditions like applied pressure and temperature. The results of different experiments have been discussed in light of break down and formation of the continuous conductive network.