Iridium-Catalyzed Synthesis of Acylpyridines by 2+2+2 Cycloaddition of Diynes with Acyl Cyanides

Hashimoto Toni; Kato Kaoru; Yano ReikoNatori TomokiMiura HirokiTakeuchi Ryo

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Iridium-Catalyzed Synthesis of Acylpyridines by 2+2+2 Cycloaddition of Diynes with Acyl Cyanides

机译：铱催化二炔与酰基氰化物的环加成反应合成酰基吡啶

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摘要

2-Acylpyridines were prepared by iridium catalyzed 2 + 2 + 2 cycloaddition of alpha,omega-diynes with acyl cyanides. Ir(cod)Cl(2)/rac-BINAP or F-DPPE is an efficient catalyst for this reaction. The scope and limitations of this reaction have been disclosed.

机译：以铱催化α，omega-二炔与酰基氰化物[2 + 2 + 2]环加成制备了2-酰基吡啶.[铋（鳕）Cl]（2）/rac-BINAP或F-DPPE是该反应的有效催化剂。该反应的范围和局限性已经公开。

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来源
《The Journal of Organic Chemistry》 |2016年第13期|5393-5400|共8页
作者
Hashimoto Toni; Kato Kaoru; Yano ReikoNatori TomokiMiura HirokiTakeuchi Ryo;
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作者单位

Aoyama Gakuin Univ, Dept Chem & Biol Sci, Chuo Ku, 5-10-1 Fuchinobe, Sagamihara, Kanagawa 2525258, Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种英语
中图分类有机化学;
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Iridium-Catalyzed Synthesis of Acylpyridines by 2+2+2 Cycloaddition of Diynes with Acyl Cyanides

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