Box-shaped nanostructures of B-C-N compounds were synthesized by reactive sputtering of boron carbide in mixed argon and nitrogen discharges. Transmission electron microscopy showed that these nanoboxes were grown on self-patterned NaCl substrate with projected areas ranging from ~1×10~(2) to ~5×10~(4) nm~(2), sizes 50-100 nm, and number density ~100 μm~(-2). Electron energy loss spectroscopy revealed a phase separation of BN and C:N layers.
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