首页> 外文期刊>journal of chemical physics >The optical activity of molecules of arbitrary size
【24h】

The optical activity of molecules of arbitrary size

机译:The optical activity of molecules of arbitrary size

获取原文
           

摘要

We determine the explicit timehyphen;dependence of a state function which initially corresponds to a molecule interacting with a single planehyphen;polarized photon. It turns out that two conditions must be met if the polarization of the photon is to remain linear but may change its orientation. One is automatically satisfied for freely oriented molecules in the absence of damping and external fields; the other yields an expression for the optical rotatory power. This expression can be applied to molecules of any size and is therefore a generalization of the Rosenfeld equation which is valid only in the longhyphen;wavelength limit. In the other extreme, ohgr;rarr;infin;, the optical activity also approaches zero, but in a manner quite different from the one that is sometimes discussed.

著录项

获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号