Heats of transport from diffusion thermoeffect measurements on binary liquid mixtures of carbon tetrachloride with benzene, toluene, 2hyphen;propanone,nhyphen;hexane, andnhyphen;octane

摘要

Measurements of heats of transport are reported for binary liquid mixtures containing carbon tetrachloride and benzene, toluene, 2hyphen;propanone,nhyphen;hexane, ornhyphen;octane at 298 K and ambient pressure. Additionally, measurements were made at 308 K for carbon tetrachloride with benzene, toluene, and 2hyphen;propanone. The corresponding heathyphen;mass Onsager coefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. These data will be used in a companion paper to report a modified Enskog method for correlation and prediction of heats of transport.