The reactions of aluminiumisopropoxide with ethyl-1-hydroxycyclohexylacetate (HOC6H10.R), ethyl-2-hydroxy-2-aryl propionate (HOCHPh.R) and ethyl-2-hydroxy-2-aryl butyrate (HOCMePh.R), where (R=CH2CO2Et), have been studied in dry benzene in different molar ratios under strictly anhydrous conditions. Products of the general composition Al(OPri)3-nLn, where L = hydroxy ester anion and n = 1–3, have been isolated and characterised on the basis of elemental analysis, molecular weight, infrared and1H n.m.r. spectral data.
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机译:异丙醇铝与乙基-1-羟基环己基乙酸乙酯(HOC6H10的反应。R)、2-羟基-2-芳基丙酸乙酯(HOCHPh.R)和2-羟基-2-芳基丁酸乙酯(HOCMePh.R),其中(R=CH2CO2Et)在严格的无水条件下以不同的摩尔比在干苯中进行了研究。一般组成 Al(OPri)3-nLn 的产物,其中 L = 羟基酯阴离子和 n = 1–3,已根据元素分析、分子量、红外和 1H n.m.r. 光谱数据进行分离和表征。
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