Photoluminescence properties of a new Eu ~(2+)-activated CaLaGa _3S _7 yellowish-green phosphor for white LED applications

摘要

A thiogallate chalcogenide phosphor CaLaGa _3S _7:Eu ~(2+) was synthesized by a solid-state reaction at 950 °C in a H _2S atmosphere. The photoluminescence excitation,emission spectra, concentration quenching, fluorescence lifetime, and thermal quenching process of the phosphor were investigated in detail. It was found that the synthesized phosphor emitted intense and broadband yellowish-green light with a peak at 554 nm. Thus, the proposed phosphor is suitable for the development of blue or near UV LED. The critical dopant concentration of Eu ~(2+) (R _c=15 ?) per unit formula was found to be 0.15 mol. At room temperature, the fluorescence lifetime of Eu ~(2+) in CaLaGa _3S _7 was found to be 0.216 μs. The activation energy for thermal quenching was 0.29 eV. The chromaticity coordinates of our phosphor is very close in color to Y _3Al _5O _(12):Ce ~(3+). Therefore, CaLaGa _3S _7:Eu ~(2+) can be a good alternative as a yellowish-green phosphor and can be used for white light generation in phosphor-converted LEDs.