Formation of oxygen complexes by ozonation of carbonaceous materials prepared from cherry stomes I. thermal effects

摘要

In this study, the feasible use of ozone to form oxygen complexes in chars prepared from cherry stones (CS) is investigated. CS were charred at 450, 600 or 900deg C for 2 h in nitrogen. Char smaples were ozonated over the 25-250deg C temperature range for 1 h. Elemental chemical analysis was effected for a few selected samples. The oxygen complexes were successfully analyzed by Fourier infrared spectroscopy 9FT-IR) and by titration methods. Thermal decomposition of ozone in the gas stream was also studied and the mechanism of the ozonation process dealt with. The ozonation treatment of CS chars was found to yield proucts with a relatively high concentration of a number of oxygen complexes. These include phenolic hydroxyl, quinonic, carboxylic acid, and ether structures. The content of lactonic structures was very low in the ozonated samples. The type and quantity of oxygen compelxes depended on the ozonatin and charring temperatures. The formation of oxygen compelxes was favored when the charring of CS was effected at 450deg C and when the ozonation of the charprepared at 600deg C was performed at 100deg C. The ozone content in the gas stream was very sensitive to the temeprature increase in the reactor. Several reaction routes have been proposed for the transformation of ethr, aromatic, and olefinic structures present in CS chars into oxygen complexes.