Experimental determination of U diffusion in α-Ti

摘要

α-spectrometry was used in order to measure the diffusion of U in bulk α-Ti in the temperature range 863-1123 K (540-850 °C). A straight Arrhenius plot was found, giving diffusion parameters Q = 297 kJ/mol and D 0 = 5 × 10~(-3)m~2/s, which are similar to the α-Ti self-diffusion ones, when measured in Ti samples with a similar impurity content than presently. This behaviour is compatible with the hypothesis of U diffusing via a vacancy-assisted mechanism in the α-Ti lattice and contrasts with older results in which the activation energy is almost a third the self-diffusion one, even lower than the vacancy formation energy.