Pseudohalobridged Pentafluorophenyl Gold-Palladium Complexes

摘要

The displacement of the tetrahydrothiophen group in PdR2(tht)2or PdR3(tht))#x2212;(R = C6F5) by cyano or thiocyanato gold(I) or gold(III) complexes leads to the formation of heteronuclear derivatives of the types RAuXPdR2(tht)#x2212;(or RAuXPdR2(PPh3)#x2212;after subsequent reaction with PPh3), (RAuX)2PdR2=, (R3AuXPdR2(tht)#x2212;, (R3AuSCN)2PdR2=, RAuCNPdR3= or R3AuSCNPdR3=.