Effects of minor Cu addition on glass-forming ability and magnetic properties of FePCBCu alloys with high saturation magnetization

摘要

The effects of minor addition of Cu on glass-forming ability (GFA), thermal stability and magnetic properties of (Fe_(0.8)P_(0.09)C_(0.09)B_(0.02))100_(-x) Cu_x (x = 0-1) alloys were investigated. The introduction of Cu slightly increases the GFA and efficiently improves the primary crystallization of α-Fe nanoparticles. The alloy with 0.3 Cu addition shows the best GFA and the fully glassy rods can be produced up to 2 mm in diameter. The saturation magnetization of the glassy sample with 0.7 Cu addition can be enhanced from 1.44 to 1.60 T after proper heat treatment due to the precipitation of α-Fe nanoparticles in the glassy matrix. The combination of large GFA and high saturation magnetization as well as low cost makes the FePCBCu alloys as a kind of promising soft magnetic materials for industrial applications.