Molecular weight distribution of the graft copolymer comprising mixtures of styrene and acrylamiae on cellulose acetate film by means of gel permeation chromatography

摘要

AbstractStyrene portion of the radiation‐induced graft copolymer comprising styrene and acrylamide was separated by acid hydrolysis and the effects of various grafting parameters (e.g., reaction time, reaction temperature, solvents, monomer composition, etc.) on molecular weight distribution were evaluated by means of gel permeation chromatography. When a single monomer or mixture of two monomers are grafted, the molecular weights is found to increase, but polymer dispersity decreases with the increase of reaction time or reaction temperature except at a higher reaction time due to the continuous enlargment of the growing chain through increased swelling and molecular motion of the trapped radicals. At higher reaction time the degradation of the graft chains lead to lower molecular weight and higher polymer dispersity. Effects of solvents (e.g., methanol, ethanol, and t‐butanol) on the molecular weight and molecular weight distribution were discussed on the basis of swelling property and chain transfer constants of the solvents. Styrene‐type graft radical being long lived compared to acrylamide type, gave long‐chain styrene graft with the increase of styrene content in the reaction mixture. A comparison of the effect of one‐and two‐component systems on a molecular weight distribution is als