Depolymerization of poly(fluoroalkyl methacrylate‐co‐methyl methacrylate) as studied with thermogravimetry

摘要

AbstractThermal behaviors of a few kinds of poly(fluoroalkyl methacrylate‐co‐methyl methacrylate) prepared by γ‐ray copolymerization were investigated by using thermogravimetric measurements together with the intermittent analysis of the gaseous products. The thermal degradation of copolymers composed of one of fluoroalkyl methacrylates of the following structures: CH2C(CH3)COOCH2(CF2CF2)nH, wheren= 1,2, and 3, and methyl methacrylate proceeded according to the depolymerization mechanism reproducing the pristine component comonomers exclusively, but their thermograms in inert atmosphere showed the feature of a two‐step reaction. In air, however, thermograms of copolymers did not show such a stepwise decrease in weight with the elevating temperature, and temperatures at which depolymerization was introduced shifted to a much higher region. The overall aspects of depolymerization of copolymers seemed to be much similar to that of fluoroalkyl methacrylate homopolymer previously reported, and the retardation of depolymerization by air was considered to be due mainly to the stabilization of once‐formed polymer radica