AbstractA new model for high‐pressure homogenization has been previously developed. A key model parameter, the mean effective cell strength, can be correlated with average cell length and peptidoglycan cross‐linkage. In this article, we develop a correlation for mean effective strength based on a statistical thermodynamic approach to fracture. The final correlation provides an unbiased estimate. While it offers no numerical advantage over a previous empirical correlation, it is based on a modeling approach and an understanding of wall structure. The variable groupings are therefore justifia
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