Mechanical and ablation properties of 2D-carbon/carbon composites pre-infiltrated with a SiC filler

摘要

In order to improve the mechanical and ablation properties of 2D-carbon/carbon composites, a SiC filler was added to a 2D-preform before isothermal chemical vapor infiltration densification by using a powder infiltration technique. Backscattered electron images showed that the SiC filler was mainly concentrated between the fiber bundles and between the layers. The tensile and flexural strengths of the composites were improved by the addition of the SiC filler because of the increase of interfacial surface areas between the bundles and between the layers, the less residual open porosity, and also the strong bonding between the SiC particles and the pyrocarbon matrix. The composites with filler experienced a 15.2 percent lower thickness erosion rate and a 51.7 percent lower mass erosion rate, compared to those C/C without filler. This was attributed to the low oxygen permeability of the SiO_2 shielding the exterior inter-bundle pores as well as to a thermal barrier effect.