Highly hydroxylated carbon fibres as electrode materials of all-vanadium redox flow battery

摘要

A highly effective hydroxylated-functionalization of carbon fibres for use as electrodes of all-vanadium redox flow battery (VRFB) was developed. Carbon paper made of carbon fibres was hydroxylated ultrasonically with mixed acids (H2SO4/HNO3) V_(H2SO4)/V_(HNO3)= 3/1) in a Teflon-lined stainless steel autoclave for different time at 80 °C. The structure, composition, and electrochemical properties of the treated samples for positive and negative electrodes of VRFB were characterized with Fourier transformation infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectrometry, scanning electron microscopy, X-ray diffraction, cyclic voltammetry, electrochemical impedance spectroscopy, and cell charge and discharge tests. The content of hydroxyl group changes from 3.8 for the untreated sample to 14.3 for the carbon paper treated in mixed acids for 10 h. The highly hydroxylated sample shows its high activity toward the redox reactions of V(II)/V(III) and V(IV)/V(V). The VRFB using the carbon paper treated for 8 h as the electrodes exhibits excellent performance under a current density of 10 mA cm~2. The average voltage efficiency reaches 91.3, and the average energy efficiency reaches 75.1. The mechanisms for the high hydroxylation of the carbon fibres with the mixed acids and the high activity of the treated sample toward the vanadium redoxs are discussed.