A complete study of CO2 line parameters around 4845 cm(-1) or Lidar applications

摘要

A diode laser spectrometer was used in the Groupe de Spectrometrie Moleculaire et Atmospherique of Reims (France) to study CO2 line intensities, self-broadening coefficients and air-pressure-broadening coefficients near 2.063 mu m. The spectral region ranging from 4843 to 4848cm(-1), which is suitable for the measurement of atmospheric carbon dioxide (CO2) mixing ratios was studied using a new generation-commercial diode laser from Nanoplus. Three lines of the (20 degrees 1)(III) (000) band of CO2 have been studied. The results of intensity measurements and self-broadening coefficients are compared with previous determinations and available databases. Furthermore, the air-broadening coefficients for these transitions are also reported and analyzed. Finally, these new parameters are used for the measurement of atmospheric CO2 mixing ratio with the 2 mu m heterodyne differential absorption Lidar from the Laboratoire de Meteorologie Dynamique at Palaiseau (France). These new parameters demonstrate a dramatic improvement of the retrieved atmospheric CO2 concentrations. (c) 2007 Elsevier Ltd. All rights reserved.