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Heavy metal contamination of soils in Northern Slovakia

机译:斯洛伐克北部土壤的重金属污染

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AbstractEnvironmental damages like forest decline in Northern Slovakia could be a result of long‐distance transport of pollutants with the dominating north‐west winds. On 10 sites, primarily in the northbound upper slopes of west‐east oriented mountain ranges in Northern Slovakia, the extent of the heavy metal contamination in soils along a north‐south transect was examined. Oi, Oe, Oa, A, and B horizons were sampled and the total concentrations of Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn were determined. The ranges of heavy metal concentrations in the forest floor were higher than reported for comparable samples from Bavarian soils except for Zn (Cd: 0.65–1.77; Cr: 12–40; Cu: 19–41; Ni: 8–24; Pb: 70–187; Zn: 31–92 mg kg−1), in the mineral soil the concentrations were lower. The depth distribution of the metal concentrations indicated a contamination with Cd, Cr, Cu, Ni, Pb, and Zn. The concentration differences between forest floor and mineral soil tended to be higher at the northern than at the southern sites for Cu, Ni, Pb, and Zn, indicating a long‐distance transport from the north. Correlation and principal component analyses of the total metal concentrations revealed three groups: Cu, Pb, and Zn inputs mainly seemed to result from long‐distance transport from the north, Cr and Ni inputs additionally from local sources. Cd probably had its origin mainly in local sources. This result was further confirmed by the grouping of
机译:摘要 斯洛伐克北部森林衰退等环境破坏可能是污染物在西北风占主导地位的长距离输送造成的。在斯洛伐克北部东西向山脉的北向上坡的10个地点,研究了沿南北样带土壤中的重金属污染程度。对Oi、Oe、Oa、A和B层进行采样,测定Al、Cd、Cr、Cu、Fe、Mn、Ni、Pb和Zn的总浓度。除锌(Cd: 0.65–1.77;铬:12-40;铜:19-41;镍:8-24;铅:70–187;Zn:31–92 mg kg−1),在矿质土壤中浓度较低。金属浓度的深度分布表明存在 Cd、Cr、Cu、Ni、Pb 和 Zn 污染。北部林地和矿物土壤的Cu、Ni、Pb和Zn浓度差异往往高于南部,表明从北方远距离迁移。对总金属浓度的相关性和主成分分析揭示了三组:Cu、Pb 和 Zn 的输入似乎主要来自北方的长距离传输,Cr 和 Ni 的输入此外来自当地来源。镉可能主要起源于当地。这一结果进一步证实了

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