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Crosslinked polyesters from allyl glycidyl ether and maleic anhydride

机译:由烯丙基缩水甘油醚和马来酸酐制成的交联聚酯

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AbstractAllyl glycidyl ether and maleic anhydride, mixed in equimolar quantities, cure together readily in the presence of air, peroxide, and/or Lewis acids. Outstanding properties of the castings formed are hardness (Barcol 50–60 at 25°C., 30 at 150°C.), clarity and heat distortion temperature (165–168°C.). Color is yellow to amber, and strength properties are adequate. Water resistance is fair. The mixture is too thin for convenient use in laminating, but it can be bodied by heating (1 hr., 110°C.), giving a syrup of 50 cpoise. In glass cloth laminates, through‐cure appears to be inhibited by the glass. The addition of styrene overcomes this effect. Small amounts are best (5–20), since large quantities impair elevated temperature strength. Unusually good strength is attained even at 500°F., but resistance to aging at 50
机译:摘要烯丙基缩水甘油醚和马来酸酐以等摩尔量混合,在空气、过氧化物和/或路易斯酸存在下很容易固化在一起。铸件的突出性能是硬度(25°C时为Barcol 50-60,150°C时为30°C),透明度和热变形温度(165-168°C)。).颜色为黄色至琥珀色,强度特性足够。耐水性一般。混合物太稀,不方便用于层压,但可以通过加热(1小时,110°C)来烘托,得到50 cpoise的糖浆。在玻璃布层压板中,贯穿固化似乎受到玻璃的抑制。苯乙烯的添加克服了这种影响。少量最好 (5-20%),因为大量会损害高温强度。即使在 500°F 时也能获得异常好的强度,但在 50°F 时仍具有耐老化性

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