Synthesis and Coordination of Tripodal‐Containing Copper(I) Complexes

摘要

AbstractReaction of copper(I) chloride with 2,2‐bis(diphenylphosphinomethyl)‐l‐phenylthiopropane P2S produced a dimeric species (P2S)CuC12(2). Treatment of 2 with silver nitrate in acetonitrile gave a hexameric crystalline metal complex {(P2S)Cu(CH3CN)6+6NO3} (4), which had a “cyclodextrin‐type” structure. A linear polymeric copper complex (P2S)Cu(NO3)nwas obtained by recrystallization of 4 in chloroform. These complexes were characterized by single crystal analyses, and their coordination behaviors in solution ar