A Scale Effect in the Durability of Oriented Thin-Wide Polypropylene Films during Oxidation under Load: Fracture Model of Stressed Polypropylene Films

摘要

Studies have been made of the durability of oriented isotactic polypropylene (PP) films depending on their width during intensive oxidation (T= 130#xB0;C, P02= 20 kPa) under load. As the specimen width decreases under low stresses, mean durability is determined thermooxidative destruction rate at the nucleation sites the scale effect takes place. The durability values are found to be discrete multiples of integers for narrow specimens. The conclusion is drawn that the difference in polymeric specimen durability is determined by the concentration of defect zones, rather than by the versatility of their nature. The model of oriented PP films fracture under low-load oxidation conditions is proposed. This model is based on the dependence of durability on a number of oxidation destruction centers which are similar in nature (in the initiation rate) and cause specimen fracture while growing and joining together.