A mutually inclined interpenetrated cobalt benzenetricarboxylate/organodiimine layered coordination polymer containing 'infinite' water chains and its irreversible crystal-to-crystal structural transformation upon dehydration

摘要

The novel coordination polymer {[Co(Hbtc)(4-bpmp)(H2O)] · 3H2O} (1,btc= 1,3,5-benzenetricarboxylate,4-bpmp = N,N'-bis(4-pyridylmethyl)piperazine) has been prepared by hydrothermal synthesis and characterized by single crystal X-ray diffraction,IR and thermogravimetric analysis. Individual [Co(Hbtc)(4-bpmp)(H2O)]_n layers mutually interpenetrate in a 2d + 2d → 3D inclined fashion to produce channels coursing down the c crystal direction,occupied by "infinite" 1D water molecule chains. Dehydration of 1 results in structural reorganization to a monoclinic phase,which is converted to an amorphous phase upon rehydration.