Designed construction of a non-interpenetrated 2D bilayer framework with large guest-clathrated channels

摘要

Manganese isophthalate [Mn(ip)]_n double-chains are deliberately combined by axial connector (E)-1,2-bis(4-pyridyl)ethylene (dpe) to construct a non-interpenetrated 2D bilayer framework which possesses large rectangular channels to trap dpe and H_2O molecules.