首页> 外文期刊>Inorganic Chemistry Communications >Hydrothermal synthesis,crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd_2(pydc)_2(H_2O)]_n (pydc=pyridine-2,3-dicarboxylate)
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Hydrothermal synthesis,crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd_2(pydc)_2(H_2O)]_n (pydc=pyridine-2,3-dicarboxylate)

机译:新型3-D配位聚合物[Cd_2(pydc)_2(H_2O)] _ n(pydc = pyridine-2,3-dicarboxylate)的水热合成,晶体结构和光致发光性能

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摘要

A novel 3-D coordination polymer [Cd_2(pydc)_2(H_2O)]_n,(pydc=pyridine-2,3-dicarboxylate) 1 has been hydrothermally synthesized and characterized by the elemental analyses,IR spectrum and the single crystal X-ray diffraction.The title compound consists of two kinds of Cd(II) center with different coordination environments by pydc and aqua ligands,to form a 3-D open framework.Compound 1 display strong fluorescent emission in the solid state at room temperature.
机译:水热合成了新型的3-D配位聚合物[Cd_2(pydc)_2(H_2O)] _ n,(pydc =吡啶-2,3-二羧酸酯)1,并通过元素分析,红外光谱和单晶X-进行了表征。标题化合物由pydc和aqua配体组成的具有不同配位环境的两种Cd(II)中心组成,形成3-D开放骨架。化合物1在室温下呈固态时发出强荧光。

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