Synthesis,crystal structure,and gas adsorption property of microporous solid by assembly of 1-D coordination polymer with a zigzag skeleton

摘要

A crystalline solid,[Rh(II)_2(bza)_4(1,5,-nptd)]_n (bza and 1,5-nptd=benzoate and 1,5-naphthyridine),was synthesized and char-acterized by single-crystal X-ray diffraction analysis;the microporous compound demonstrates gas adsorbency with a N_2 BET surface area of 291.6 m~2 g~(-1).