Synthesis of Six New Substituted Aminomethylglyoximes and Some of Their Transition Metal Complexes

摘要

The following substituted amino and diaminomethylglyoximes have been synthesized: phenylaminomethylglyoxime, p-tolylaminomethylglyoxime, p-acetoxy-phenylaminomethylglyoxime, diphenyl-4,4′-bis(aminomethylglyoxime), l,l′-diphenyl-methane-4,4′-bis(aminomethylglyoxime) and 1,1′-diphenyloxy-4,4′-bis(aminomethyl-glyoxime) Their complexes with cobalt(II), nickel(II), copper(II) and palladium(II) have been isolated. The structure of these new compounds are proposed on the basis of elemental analyses,1H-NMR and IR spectral data.