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Lipase/enzyme catalyzed biodiesel production from Prunus mahaleb: A comparative study with base catalyzed biodiesel production

机译:李氏脂肪酶/酶催化生物柴油生产:与碱催化生物柴油生产的比较研究

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摘要

Many industrial applications involve the transesterification of natural oils and fats. In the present work, methyl esters were transesterified from white mahlab oil (WMO) using methanol via base and lipase-catalyzed reactions. The oil content of the mahlab seeds was found to be 31%. The composition of the fatty acid methyl esters (FAMEs) produced from the WMO was analyzed by GC/MS, revealed alpha-eleostearic acid (40.7%), oleic acid (29.8%) and linoleic acid (26.6%). The effects of the reaction conditions (i.e., time, temperature, the amount of catalyst, methanol/oil molar ratio, water content and the amount of solvent) on FAME's yield were appraised. The important fuel properties of the FAME's were measured and compared with ASTM 6751 and EN 14214 biodiesel standards. (C) 2015 Elsevier B.V. All rights reserved.
机译:许多工业应用涉及天然油脂的酯交换。在目前的工作中,使用甲醇通过碱和脂肪酶催化的反应,从白色马哈伯油(WMO)中将甲酯进行酯交换。发现mahlab种子的油含量为31%。通过GC / MS分析了WMO生产的脂肪酸甲酯(FAME)的组成,发现α-硬脂酸(40.7%),油酸(29.8%)和亚油酸(26.6%)。评价了反应条件(即时间,温度,催化剂量,甲醇/油摩尔比,水含量和溶剂量)对FAME收率的影响。测量了FAME的重要燃料特性,并与ASTM 6751和EN 14214生物柴油标准进行了比较。 (C)2015 Elsevier B.V.保留所有权利。

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