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Fabrication of a high hydrophobic PVDF membrane via nonsolvent induced phase separation

机译:通过非溶剂诱导相分离制备高疏水性PVDF膜

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摘要

The aim of this paper is to prepare a PVDF(polyvinylidene fluoride)microporous membrane by using alcohol as nonsolvent(coagulant).A porous membrane with high hydrophobic surface(water contact angle ~148°)was facilely created by wet immersion method without modification with special low surface energy compounds and the need of special instruments.In addition,the PVDF casting film was passed through alcohol bath for 2 s and then immersed into water precipitation bath,the porous PVDF membrane with hydrophobic surface(water contact angle ~135°)was also formed.The characterization of the porous PVDF membrane obtained from various coagulation conditions was carried out by a pore size analysis and a direct contact membrane distillation(DCMD).The permeation flux and rejection coefficient of the porous PVDF membrane fabricated via dual-bath coagulated was close to commercial one.
机译:本文的目的是以醇为非溶剂(凝固剂)制备PVDF(聚偏氟乙烯)微孔膜。采用湿浸法,无需改性,无需特殊低表面能化合物,无需特殊仪器,便捷制备了高疏水表面(水接触角~148°)的多孔膜。此外,将PVDF流延膜通过醇浴2 s,然后浸入水沉淀浴中,形成疏水表面(水接触角~135°)的多孔PVDF膜。通过孔径分析和直接接触膜蒸馏(DCMD)对不同混凝条件下得到的多孔PVDF膜进行了表征。双浴凝固制备的多孔PVDF膜的渗透通量和抑制系数接近商业化。

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