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The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles

机译:利用氧化石墨生产介孔碳支持Pt、Ru或Pd纳米颗粒

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摘要

Mesoporous carbon having platinum, ruthenium or palladium nanoparticles on exfoliated graphene sheets were produced from graphite oxide (GO) and metal complexes. The Pt included carbon was made by heating of the intercalation compound including tetraam-mineplatinum (II) chloride monohydrate. Samples having Ru or Pd are producible by heating in nitrogen gas atmosphere using hexaammineruthenium (III) chloride or tetraam-minepalladium (II) chloride monohydrate instead of Pt complex. The particle sizes of platinum, ruthenium, and palladium were, respectively, 1-3,1-2, and 3-7 nm. The platinum- or palladium-containing sample showed catalytic activity for oxygen reduction.
机译:由氧化石墨 (GO) 和金属配合物制备了在剥离的石墨烯片上具有铂、钌或钯纳米颗粒的介孔碳。Pt含碳是通过加热包括四胺矿铂(II)氯化物一水合物的插层化合物制成的。具有Ru或Pd的样品可以通过使用六氨基氯化钌(III)或四胺-氯化钯(II)一水合物代替Pt络合物在氮气气氛中加热来生产。铂、钌和钯的粒径分别为1-3、1-2和3-7 nm。含铂或钯样品具有催化氧还原活性。

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