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Mid-infrared absorption cross-sections and temperature dependence of CFC-113

机译:CFC-113的中红外吸收截面和温度依赖性

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摘要

The temperature dependence of the infrared absorption cross-sections of CFC-113 (1,1,2-trichlorotrifluoroethane) in a pure vapor phase has been recorded in the 600-1250cm~(-1) spectral region using Fourier transform spectroscopy. Spectra at 0.05cm~(-1) resolution have been used to derive the integrated band strengths of the five main absorption bands over a range of temperatures from 223 to 283K. Our results show good agreement with previously published data. The new cross-sections will allow more accurate retrieval of atmospheric CFC-113 concentrations using infrared spectroscopic techniques.
机译:采用傅里叶变换光谱法记录了CFC-113(1,1,2-三氯三氟乙烷)在纯气相中红外吸收截面的温度依赖性。利用分辨率为0.05cm~(-1)的光谱,推导了5个主要吸收带在223至283K温度范围内的积分能带强度。我们的结果与先前发表的数据非常吻合。新的横截面将允许使用红外光谱技术更准确地检索大气中的CFC-113浓度。

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