Abstractp‐Chlorophenyl methylcarbamate (PCMC) underwent spontaneous hydrolysis in aqueous solution top‐chlorophenol with concomitant loss of ability to inhibit hydrolysis of the phenylcarbamate isopropyl phenylcarbamate (propham). A phenylcarbamate‐degrading soilArthrobactersp. had no direct effect on PCMC itself but formed 4‐chlorocatechol during the metabolism ofp‐chl
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