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Soft mode analysis and ferroelectric transition in spherical nanoparticles

机译:球形纳米颗粒的软模态分析与铁电跃迁

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摘要

We address the dielectric behavior in a free standing spherical particle using the phenomenological Landau theory. Considering the equations of motion and small perturbation against uniform polarization, we obtain the size driven ferroelectricity. The size driven polarization is shown to diverge at a new correlation length which turns out to be the extrapolation length. Mode analysis in such systems is carried out and it is found that the size driven ferroelectricity is associated with a soft mode which takes a minimum value at the new transition temperature similar to that of the bulk system. We suggested that such a mode can be tested in Raman measurement.
机译:我们使用现象学朗道理论解决了独立球形粒子中的介电行为。考虑均匀极化的运动方程和小扰动,我们得到了尺寸驱动的铁电性。尺寸驱动的极化在新的相关长度处发散,该长度被证明是外推长度。对此类体系进行了模态分析,发现尺寸驱动的铁电性与软模态有关,软模态在新的转变温度下具有与体系相似的最小值。我们建议可以在拉曼测量中测试这种模式。

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