AbstractA series of polymer blend membranes with several weight ratios of poly(vinyl chloride) (PVC) and oligo(dimethylsiloxane) (ODMS) were prepared and the permeation behaviors of O2and N2were studied. These components are only partially miscible to each other, leading to a phase separation. In order to improve the compatibility of these polymer blends, the use of a graft copolymer PVC‐g‐ODMS was explored. The gas permeation studies, the thermal analyses, and the microscopic observations were made on PVC‐g‐ODMS/ODMS blend membranes, and the results indicate that these blend membranes have rather high gas permeabilities together with good mechanical pro
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