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Novel synthesis of substituted cyclopropane acetic acid ethyl esters from cyclopropyl alkyl ketones

机译:由环丙基烷基酮新型合成取代的环丙烷乙酸乙酯

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摘要

The cyclopropane acetic acid ethyl esters 2 have been conveniently prepared in one step from cyclopropyl alkyl ketones 1 by reacting with lead(IV)acetate in triethyl orthoformate in the presence of 70% perchloric acid.In all these reactions triethyl orthoformate is used as the solvent.
机译:在70%高氯酸存在下,通过与乙酸铅(IV)在原甲酸三乙酯中反应,可以方便地从环丙基烷基酮1一步制备环丙烷乙酸乙酯2.在所有这些反应中,将原甲酸三乙酯用作溶剂。

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