首页> 外文期刊>Indian Journal of Chemistry, Section A. Inorganic, Physical, Theoretical & Analytical >Role of heterogeneous reactions in generating chaos and noise in oscillatory chemical reactions
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Role of heterogeneous reactions in generating chaos and noise in oscillatory chemical reactions

机译:异质反应在振荡化学反应中产生混沌和噪声中的作用

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摘要

In view of the importance of noise in physiology,information processing and finance,studies on chaos and noise have been undertaken.Detailed studies on the following oscillatory reactions have been undertaken:(i) thiophenol+BrO_3+H_2SO_4,(ii) fructose+BrO_3+H_2SO_4+Ce~(4+),and (iii) iodate+arsenite,which can serve as a model system for this purpose.Aperiodic oscillations have been observed in these systems.Analysis of phase plane plots yields complex attractors,which are quite different from strange attractor indicating the occurrence of random noise.Power spectra also indicate chaos with a broad band not necessarily the deterministic chaos.For the reactions (i) and (iii),a mechanism has been proposed involving precipitation of C_6-H_5-S-C_6H_5 and iodine,respectively;while in case of reaction (ii),gaseous evolution of Br_2 has been invoked.Experimental studies on sedimentation of C_6H_5-S-C_6H_5 and Br_2 evolution confirm that such heterogeneous reactions play an important role in generating noise in oscillations.
机译:鉴于噪声在生理学,信息处理和财务方面的重要性,已进行了有关混沌和噪声的研究。对以下振荡反应进行了详细研究:(i)硫酚+ BrO_3 + H_2SO_4,(ii)果糖+ BrO_3 + H_2SO_4 + Ce〜(4+)和(iii)碘酸盐+亚砷酸盐可以用作模型系统。在这些系统中已观察到非周期性振荡。相平面图的分析产生了复杂的吸引子与奇怪的吸引子不同,它表明随机噪声的出现。功率谱还表明具有宽频带的混沌,不一定是确定性的混沌。对于反应(i)和(iii),提出了一种涉及C_6-H_5-S沉淀的机理-C_6H_5和碘;分别在反应(ii)的情况下调用了Br_2的气态析出。对C_6H_5-S-C_6H_5和Br_2析出的沉积实验研究证实,这种异质反应在gen中起着重要作用。振荡中发出的噪音。

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