Molecuar complexity from aromatics: Synthesis of embellished endo tricyclo[5.2.2.0]undecanes

Vishwakarma Singh; Dilip K Tosh

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Molecuar complexity from aromatics: Synthesis of embellished endo tricyclo[5.2.2.0]undecanes

机译：芳香族化合物的分子复杂性：带修饰的内环三环[5.2.2.0]十一烷的合成

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Synthesis of the tricyclic keto-epoxides 2 and 3 from the readily available aromatic precursors 4,5respectively, via generation and interception of spiroepoxycyclohexa-2,4-dienones is described.

机译：描述了通过螺环环氧环己-2,4-二壬烯的产生和截获分别从容易获得的芳族前体4,5合成三环酮-环氧化物2和3。

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《Indian Journal of Chemistry, Section B. Organic Including Medicinal》 |2003年第4期|共3页
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Vishwakarma Singh; Dilip K Tosh;
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正文语种 eng
中图分类化学;化学工业;
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1. Molecuar complexity from aromatics: Synthesis of embellished endo tricyclo[5.2.2.0]undecanes [J] . Vishwakarma Singh, Dilip K Tosh Indian Journal of Chemistry, Section B. Organic Including Medicinal . 2003,第4期

机译：芳香族化合物的分子复杂性：带修饰的内环三环[5.2.2.0]十一烷的合成
2. Aromatics to riquinanes. Synthesis and photoreaction of tricyclo[5.2.2.0~2.6]undecanes having an α-methoxy β,γ-unsaturated carbonyl chromophore [J] . Vishwakarma Singh, Beena Thomas The Journal of Organic Chemistry . 1997,第16期

机译：芳基到芳烃。具有α-甲氧基β，γ-不饱和羰基发色团的三环[5.2.2.0〜2.6]十一烷的合成与光反应
3. Molecular Complexity from Aromatics: A Novel, Stereoselective Route to Tricyclo[5.2.2.0~(1,5)]undecenones, Tricyclo[6.2.2.0~(1,6)]Dodecenones, and [n.3.3]Propellanes [J] . Vishwakarma Singh, Pramod K. Sahu, Raj Bahadur Singh The Journal of Organic Chemistry . 2007,第26期

机译：芳香族化合物的分子复杂性：一种新颖的立体选择路线，可合成三环[5.2.2.0〜（1,5）]十一碳烯，三环[6.2.2.0〜（1,6）]十二碳烯和[n.3.3]丙烷
4. SYNTHESIS OF THE OPTICALLY ACTIVE FORMS OF 4,10-DIHYDROXY-1,7-DIOXASPIRO 5,5 UNDECANE AND THEIR CONVERSION TO THE ENANTIOMERS OF 1,7-DIOXASPIRO5.5UNDECANE, THE OLIVE FLY PHEROMONE [C] . T. Uematsu, K.Mori International Congress of Pesticide Chemistry . 1986

机译：合成4,10-二羟基-1,7-Dioxaspiro 5,5的非甲烷的光学活性形式及其转化为1,7-二氧化硅的对映体5.5未甲烷，橄榄蝇信息素
5. THE CHEMISTRY OF ENDO-TRICYCLO O(2,7)UNDEC-9-EN-3,6-DIONE: PRECURSOR FOR THE SYNTHESIS OF THE BCD RING SYSTEM OF PHYLLOCLADENE. [D] . GREEN, LINDA LEDBETTER. 1969

机译：内-三环O（2,7）UNDEC-9-EN-3,6-dione的化学性质：番茄红素BCD环系统的合成前体。
6. NN′-(8-endo11-endo-Dihydroxypentacyclo5.4.0.026.0310.059undecane-811-diyl)bis(methylenecarbonyl)di-l-phenylalanine [O] . Rajshekhar Karpoormath, Patrick Govender, Hendrik G. Kruger, 2010

机译：-1-苯丙氨酸的NN-（（8-内内--11-二羟基五环5.4.0.026.0310.059十一烷-811-二基）双（亚甲基羰基）
7. Synthesis of some novel 4-aza-tricyclo5.2.2.0 2,6 undecane-3,5,8-triones from 2-trimethylsilyloxy-1,3-cyclohexadiene and 1-methoxy-1,3-cyclohexadiene [O] . Hosapalya Thimmaiah Srinivasa, Hari Prasad Suresh 2012

机译：从2-三甲基甲硅烷氧基-1,3-环己二烯和1-甲氧基-1,3-环己二烯合成一些新的4-氮杂 - 三环5.2.2.0 2,6十一烷-3,5,8-三酮
8. Synthesis of the Two Epimeric 6-Carbomethoxy-1,5-Dimethyl-endo-tricyclo(5.2.1.0(2,6))dec-8-en-3-0nes. Unequivocal Structural Assignment of the 5-Alpha-and 5Beta-Isomers via Two-Dimensional NMR Spectroscopy [R] . Smith, W. B., Marchand, A. P., Suri, S. C., 1986

机译：合成两个差向异构体-6-甲氧基-1,5-二甲基 - 内 - 三环（5.2.1.0（2,6））癸-8-烯-3-0nes。通过二维NmR光谱法对5-α和5Beta-异构体进行明确的结构分配

Molecuar complexity from aromatics: Synthesis of embellished endo tricyclo[5.2.2.0]undecanes

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