A convenient synthesis of 2-fluoro-#alpha#-methyl[1,1'-biphenyl]-4-acetic acid via rearrangement of aryl ketones

A V Pol; A Sudalai; H R. Sonawane

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A convenient synthesis of 2-fluoro-#alpha#-methyl[1,1'-biphenyl]-4-acetic acid via rearrangement of aryl ketones

机译：通过芳基酮的重排方便地合成2-氟-＃α＃-甲基[1,1'-联苯] -4-乙酸

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摘要

The rearrangement of various meta-substituted p-cyclohexyl aryl ketones has been investigated with the objective to develop a convenient route for the synthesis of 2-fluoro-#alpha#-methyl [1,1'-biphenyl-4-acetic aicvd [(+-)-flurbiprofen],a potent anti-inflammatory agent of current importance.

机译：已经研究了各种间位取代的对-环己基芳基酮的重排，目的是为合成2-氟-＃α＃-甲基[1,1'-联苯-4-乙酸] [[（ +-）-氟比洛芬]，一种当前重要的有效抗炎药。

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《Indian Journal of Chemistry, Section B. Organic Including Medicinal》 |1998年第3期|共8页
作者
A V Pol; A Sudalai; H R. Sonawane;
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正文语种 eng
中图分类化学;化学工业;
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1. A convenient synthesis of 2-fluoro-#alpha#-methyl[1,1'-biphenyl]-4-acetic acid via rearrangement of aryl ketones [J] . A V Pol, A Sudalai, H R. Sonawane Indian Journal of Chemistry, Section B. Organic Including Medicinal . 1998,第3期

机译：通过芳基酮的重排方便地合成2-氟-＃α＃-甲基[1,1'-联苯] -4-乙酸
2. SYNTHESIS AND CHARACTERIZATION OF ARYL AMINE DERIVATIVES OF 1,1'-BIPHENYL 2,2'-DICARBOXYLIC ACID AND STUDY OF ANTIBACTERIAL AND ANTIFUNGAL ACTIVITIES [J] . Vikram Kumar Gupta, B.K.Shrivastava Oriental Journal of Chemistry: An International Research Journal of Pure & Applied Chemistry . 2005,第3期

机译：1,1'-联苯2,2'-二羧酸的芳胺衍生物的合成，表征及抗菌和抗真菌活性的研究
3. An improved synthesis of hydroxy aryl ketones by fries rearrangement with methanesulfonic acid/methanesulfonic anhydride [J] . Jeon I., Mangion I.K. Synlett . 2012,第13期

机译：通过甲磺酸/甲磺酸酐的弗里斯重排来改进羟基芳基酮的合成
4. Curtius rearrangement and Schmidt reaction as convenient methods in the synthesis of non-protein amino acids.(Abstracts) [C] . Bozena Frackowiak, Kamila Gajcy, Agnieszka Kusiak European Symposium on Organic Chemistry . 2007

机译：Curtius重排和Schmidt反应是在合成非蛋白质氨基酸的方便方法中。（摘要）
5. STUDIES IN STEREOCHEMISTRY. PART I: SYNTHESIS, RESOLUTION AND ABSOLUTE CONFIGURATION OF (E)-2,4-DIMETHYL-2-HEXENOIC ACID. PART II: THE DETERMINATION OF THE HEAT OF HYDROGENATION AND REARRANGEMENT BEHAVIOR OF 1,1'-SPIROBIINDENE. PART III: SYNTHESIS AND CHIROPTICAL PROPERTIES OF 5,7-DIOXOBICYCLO(2.2.2)OCT-2-ENE AND BICYCLO(2.2.2)OCTAN-2,5-DIONE. [D] . MORTON, GERALD HUNT. 1980

机译：立体化学研究。第一部分：（E）-2,4-二甲基-2-己酸的合成，拆分和绝对构型。第二部分：1,1'-螺双茚的加氢热和重排行为的测定。第三部分：5,7-二氧杂双环（2.2.2）OCT-2-烯和双环（2.2.2）OCTAN-2,5-二酮的合成和手性。
6. Carbonylative Cross-Coupling of ortho-Disubstituted Aryl Iodides. Convenient Synthesis of Sterically Hindered Aryl Ketones [O] . B. Michael O’Keefe, Nicholas Simmons, Stephen F. Martin -1

机译：邻二取代芳基碘化物的羰基交叉偶联。立体受阻芳基酮的便捷合成
7. Oxidative rearrangement of alkyl aryl /heteroaryl ketones by 1,2-aryl/heteroaryl shift using iodic acid [O] . Krishnacharya G. Akamnachi, Sameerana N. Huddar, Swapnil S. Deshmukh 2010

机译：使用碘酸通过1,2-芳基/杂芳基位移氧化重排烷基芳基/杂芳基酮

A convenient synthesis of 2-fluoro-#alpha#-methyl[1,1'-biphenyl]-4-acetic acid via rearrangement of aryl ketones

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