03 to 01 Phase Transitions in Highly Delithiated NMC811 at Elevated Temperatures

摘要

Nickel-rich layered oxide cathodes such as NMC811 (LixNi0.8Mn0.1Co0.1O2) currently have the highest practical capacities of cathodes used commercially,approaching 200 mAh/g. Lithium is removed from NMC811 via a solid-solution behavior when delithiated to xLi > 0.10,maintaining the same layered (03 structure) throughout as observed via operando diffraction measurements. Although it is possible to further delithiate NMC811,it is kinetically challenging,and there are significant side reactions between the electrolyte and cathode surface. Here,small format,NMC811-graphite pouch cells were charged to high voltages at elevated temperatures and held for days to access high states of delithiation. Rietveld refinements on high-resolution diffraction data and indexing of selected area electron diffraction patterns,both acquired ex situ,show that NMC811 undergoes a partial and reversible transition from the 03 to the Ol phase under these conditions. The Ol phase fraction depends not only on the concentration of intercalated lithium but also on the hold temperature and hold time,indicating that the phase transition is kinetically controlled. 'H NMR spectroscopy shows that the proton concentration decreases with Ol phase fraction and is not,therefore,likely to be driving the 03—Ol phase transition.