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Photocatalytic Properties of TiO2 for the Degradation of O3: Examined by Environmental Parameters

机译:TiO2 降解 O3 的光催化性能:通过环境参数进行研究

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Background: This paper describes how environmentally relevant parameters affect titanium dioxide's photocatalytic properties (TiO2) to decompose ozone (O3). Methods: Thus, experiments have been carried out in a box chamber with TiO2 coated roofing membrane samples to determine the significance of light intensity, temperature, initial O3 concentration, and relative humidity. Furthermore, an outdoor experiment was conducted where the roofing membrane was subjected to natural sunlight. Results: The results show a significant photocatalytic effect of TiO2. The half-life of the O3 decay curve is 5.8 min in near-ambient UV-light exposure compared with 7.1 min in dark conditions. Experiments conducted at higher light intensity show a more extensive degradation of O3, where the value of the reactive uptake coefficient increases from 0.044 to 0.051. Also, the measurements carried out under natural sunlight show a photocatalytic effect where the uptake coefficient value is 0.046. A larger photocatalytic effect is detected for the experiments conducted at 283 K and 303 K temperatures compared with experiments under standard conditions. Conclusion: Experiments carried out with a very high initial concentration of O3 show that 28.1 μg of O3 is decomposed in ambient conditions, where 2.3 μg is destroyed. This demonstrates that light intensity, temperature, ozone concentration, and relative humidity significantly impact TiO2's degradation of O3.
机译:背景:本文描述了环境相关参数如何影响二氧化钛分解臭氧(O3)的光催化性能(TiO2)。方法:因此,在装有TiO2涂层屋面膜样品的箱室中进行实验,以确定光强度、温度、初始O3浓度和相对湿度的意义。此外,还进行了室外实验,使屋顶膜受到自然阳光照射。结果:结果表明,TiO2具有显著的光催化作用。在近环境紫外光照射下,O3衰减曲线的半衰期为5.8分钟,而在黑暗条件下为7.1分钟。在较高光强度下进行的实验表明,O3的降解范围更广,反应吸收系数的值从0.044增加到0.051。此外,在自然阳光下进行的测量显示出光催化效应,其中吸收系数值为0.046。与标准条件下的实验相比,在283 K和303 K温度下进行的实验检测到更大的光催化效应。结论:在非常高的O3初始浓度下进行的实验表明,在环境条件下,28.1 μg的O3被分解,其中2.3 μg被破坏。这表明光强度、温度、臭氧浓度和相对湿度对TiO2对O3的降解有显著影响。

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